Carl Barus on Entropy (thermodynamics)

“Of the Planck molecular oscillators... If operating continuously under the established electromagnetic laws they lead to the impossible distributions of energy in the spectrum investigated by Rayleigh and Jeans. But if emitting only, when their energy content is a whole number of energy elements, a case thus involving the entropy probability of Boltzmann, Wien's law and the numerical data referred to are deducible with astounding precision.”

“The first step came from W. Wien, whose displacement law of 1893 is embodied in the shift of the maximum of spectrum energy density, from red to violet, with increasing temperatures. Wien showed that a universal function of the ratio of temperature to frequency must here be in question. The determination of this universal function was the culmination of the insight and consistent labors of Planck (1900), who by postulating the energy quantum, became the creator of modern thermodynamics; for this energy element is a saucy reality, whose purpose is to stay. It not only tells us all we know of the distribution of energy in the black body spectrum in its thermal relations, but it gives us, indirectly, perhaps the most accurate data at hand of the number of molecules per normal cubic centimeter of the gas, of the mean translational energy of its molecules, of the molecular mass, of the Boltzmann entropy constant, even of the charge of the electron or electric atom itself.”